Techniques for the Study of Ion-Molecule ReactionsJames M. Farrar, William H. Saunders The first comprehensive collection of all the major techniques used to study gas phase interactions is presented in this volume. With complete coverage of what a given technique can accomplish, its advantages and disadvantages, the book is designed to teach advanced students and researchers entering the field how to investigate a broad range of topics. Included is coverage of traditional topics such as ion cyclotron resonance, as well as more recent innovations, including Fourier transform mass spectrometry and ionic cluster studies. Several diagrams of instrumentation and examples of experimental data are also provided. |
Common terms and phrases
1-butene afterglow afterglow plasma analyzer apparatus atoms B. S. Freiser carrier gas cation Chem collision energies collisional cross sections cyclotron decay detection detector determined dissociation drift EBFlow Ec.m ejection electric field electron affinities electron beam electron gun electron impact electron transfer emission equilibria excitation experimental experiments filament flow tube frequency FTMS H₂ ICR cell ion beam ion intensities Ion Phys ion source ion-molecule reactions ion-neutral ionic ionization J. L. Beauchamp Kebarle kinetic energy laser Lett magnetic field Mass Spectrom measured method molecular molecules multitritiated N. G. Adams N₂ negative ions neutral products number density observed obtained photodissociation photoionization PHPMS plates positive ions potential pressure product ions proton pulsed pump quadrupole radiolysis rate coefficients rate constant ratio reactant reactant ion reaction vessel region resolution shown in Fig SIFT slit species spectra spectrometer spectrum studies technique temperature thermal torr transfer reactions trapping tritium velocity vibrational voltage yield