The Hole-equivalence Principle, the Van Vleck Relation and the Application to the Theory of D-ions in Ligand FieldsRijksuniversiteit Leiden, 1965 - 91 pages |
Common terms and phrases
ABRAGAM and PRYCE acting on spin antisymmetrization bČ)k choice of basis closed shell configuration dč Coulomb interaction covalent bonds d-ions in Ligand diagonal eigenstates energy levels Er₁ ET₁ fine structure constants formulae free ions g factors GRIFFITH groep group G half-closed shell hamiltonian high spin Hole Equivalence Principle hyper fine structure irreducible representation kunnen level of dČ matrix elements maximal S₂ octahedral component octahedral field octahedral Ligand fields octahedral symmetry one-electron hamiltonian one-electron operators operators not acting orbital angular momentum orthonormal basis parameters parity partly filled shell Phys Proc properties with respect PRYCE 16 quadrupole coupling RACAH second order contribution Slater determinants span spin hamiltonian spin orbit coupling splitting strong field approximation T₂ level tetragonal field tetragonal symmetry theory of d-ions toestanden transformation properties trigonal trigonal field trigonal symmetry two-electron operators u₁ unitary transformation Vleck relation weak field zijn