Ultrafast Dynamics of Chemical Systems

Front Cover
J.D. Simon
Springer Science & Business Media, Feb 28, 1994 - Science - 385 pages
The last decade has witnessed significant advances in the ability to generate short light pulses throughout the optical spectrum. These developments have had a tremendous impact on the field of chemical dynamics. Fundamental questions concerning chemical reactions, once thought to be unaddressable, are now easily studied in real-time experiments. Ultrafast spectroscopies are currently being used to study a variety of fundamental chemical phenomena. This book focuses on some of the experimental and associated theoretical studies of reactions in clusters, liquid and solid media. Many of the advances in our understanding of the fundamental details of chemical reactivity result from the interplay of experiment and theory. This theme is present in many of the chapters, indicating the pervasiveness of a combined approach for eludicating molecular models of chemical reactions. With parallel developments in computer simulation, complex chemical sys tems are being studied at a molecular level. The discussions presented in this book recount many areas at the forefront of "ultrafast chemistry". They serve the purpose of both bringing the expert up to date with the work being done in many laboratories as well as introducing those not directly involved in this field to the diverse set of problems that can be studied. I hope that this book conveys the excitement that both I and the other authors in this volume feel about the field of ultrafast chemistry. John D. Simon 1993 1.D. Simon (ed.), Ultrafast Dynamics of Chemical Systems, vii.
 

Selected pages

Contents

1 Introduction to Ultrafast Laser Spectroscopic Techniques Used in the Investigation of Condensed Phase Chemical Reactivity
1
Theory and Experiment
37
3 Ultrafast Electron and Proton Reactivity in Molecular Liquids
81
4 The Dynamics of Anion Solvation in Alcohols
137
Semiconductor Interfaces
163
6 Ultrafast Transient Raman Investigations of Condensed Phase Dynamics
205
Role of Contact Radical Ion Pairs and Solvent Separated Radical Ion Pairs
223
8 The Molecular Basis of Solvent Caging
235
9 Dielectric Continuum Models of SoluteSolvent Interactions
249
10 Analysis of Condensed Phase Photochemical Reaction Mechanisms with Resonance Raman Spectroscopy
267
Solvation at the Single Molecule Level
289
12 Quantum Brownian Oscillator Analysis of PumpProbe Spectroscopy in the Condensed Phase
327
13 Charge Transfer Reactions and Solvation Dynamics
345
Index
383
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