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affinity antisymmetric balance equation becomes binary Boltzmann equation Chapter chemical equilibrium chemical potential chemical reactions components conservation consider constant coordinates correlation function defined definition density derived differential equation diffusion coefficients diffusion flow distribution function effect electric Enskog entropy flux entropy production entropy source strength equation of motion expression fluctuation dissipation theorem fluid fluxes and thermodynamic follows formula gases given grad gradient heat conduction heat flow independent integral introduced irreversible processes isotropic kinetic theory macroscopic magnetic field matrix Mazur mechanical equilibrium mixture molar non-equilibrium thermodynamics obtain Onsager reciprocal relations Onsager relations phase space phenomena phenomenological coefficients phenomenological equations Phys Physica polarization pressure tensor Prigogine quantities relaxation result right-hand side S. R. de Groot scalar stationary sub-system symmetric temperature theorem thermo thermodynamic forces tion transformation unit mass valid values vanishes variables vector velocity viscous volume write zero