The Organometallic Chemistry of the Transition MetalsPresents organometallic chemistry within a logical framework of fundamental ideas. Deals with practical applications of the subject, processes of industrial significance, and organic synthesis. The biological aspects of the subject, which are just beginning to emerge, are also covered. Discusses methods of characterization and of bio-organometallic chemistry, neither of which is treated in the standard texts available. There is also coverage of high valent organometallic species and of applications to organic synthesis. |
Contents
Introduction | 1 |
General Properties of Organometallic Complexes | 20 |
The MetalCarbon and MetalHydrogen Bonds | 38 |
Copyright | |
19 other sections not shown
Common terms and phrases
abstraction active acyl agostic aldehyde alkane alkyl group alkyne allyl anion arene atom back donation bind bridging butadiene C-H bond carbene carbon carbon carbonyl catalyst cationic Chapter Chem chemical cluster CO₂ coenzyme Comm compounds coordinated covalent cyclometalation deprotonation dissociate donor electron count electrophilic enantiomer energy enzyme ethylene example Fischer give H₂ H₂O halide hydride hydrogenation Inorg intermediate ionic isolobal isomerization isomers Lewis acid ligand lone pair M-M bonds mechanism metal alkyls metal complexes metal fragment methyl molecule N₂ nucleophilic attack orbitals organic Organomet organometallic chemistry oxidative addition phosphine PMe3 polyene polyhydrides PPh3 protons R. H. Crabtree R. R. Schrock radical reaction reactive reacts reagent rearrangement reductive elimination resonance Section shift shown in Eq shows solvent species spectrum ẞ-elimination stable stereochemistry structure substitution substrate synthesis t-Bu thermodynamic trans transition metal unsaturated usually ос Ср