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Adatom Migration and Cluster Growth and Decay
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adatom adsorbed adsorption energy approximation atomistic atoms binding energy calculated capture rate Chapter classical model cluster density cluster edge cluster mobility coalescence condensation coefficient constant crystal crystallite decay decreases depends deposition desorption diffusion distance direct impingement distribution Donohoe epitaxial equilibrium evaluated evaporation experimental results film flux given by equation gives gradient growth rate growth-coalescence incidence rate increases incremental synthesis initial island lattice model Lewis lines maximum measurements migration molecules monolayers monomer density NaCl nmax nucleation and growth nucleation density nucleation rate nuclei obtained occurs orientation parameters partition function planar sites plotted in Fig Poppa preferred sites radius rate equations ratio region Robinson and Robins saturation Schmeisser Section shown in Fig shows size-dependent small clusters solutions spherical cap sticking coefficient Stowell substrate supercritical clusters supersaturation surface coverage surface diffusion surface energy Table tion transition treatment values vapour variation Venables Walton Zinsmeister