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Thermodynamics and Kinetics of
Kinetics of Chemical Reactions of Stressed
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absorption acid aerosil alkyl amorphous areas changes Chem chemical reactions coefficient compounds concentration crystalline curve decay decomposition decrease deformation density dependence depolymerization diffusion dissociation Dokl E.R. Klinshpont effect electrolytes energy equation equilibrium ESR spectrum experimental exposure to light Figure filler films formation free radicals free valence G.B. Pariiskii G.E. Zaikov groups hydrogen bonds hydrophilic increase initial Khim kinetics linear low-molecular macromolecules macroradicals main chain Mel'nikov molecular weight Moscow N.V. Fock nitrogen dioxide Nylon-6 oriented stretching oxidation oxygen ozone PAAm parameters peroxide radicals peroxynitrate phase photochemical reactions photodissociation photolysis photoradical ageing photoradical chain Phys PMMA poly polyamide polymer polymeric polymethacrylates polyolefins polypropylene PTFE quantum yields radicals R3 radiolysis range rate constant RcO2 reactions of radicals reactivity rupture Russian samples scission Shlyapnikov sorption spectra SSSR stress structure Table temperature thermodynamic tion Toptygin transition V.K. Milinchuk values Vysokomol Vysokomolek