Polymers in aqueous media: performance through association
J. Edward Glass, American Chemical Society. Division of Polymeric Materials: Science and Engineering
American Chemical Society, 1989 - Science - 575 pages
This volume is the first systematic review of surfactant-modified, water-soluble polymers. The authors, representing leaders in their fields, offer practical information about associative thickeners and polymer surfactants, including spectroscopic and rheological analysis of these water-soluble polymers in aqueous solutions. In addition, aqueous gels of varying chemical types are studied with respect to their properties in numerous applications. Among the topics covered are: aqueous gels; surfactant-modified, water-soluble polymers; polyelectrolyte synthesis; elongational viscosity; and fluorescence phenomena of water-soluble polymers.
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Structure and Swelling of Some Synthetic Semisynthetic
Cooperative Diffusion in WaterSwellable Polymeric Networks
Semicrystalline PoIyvinyl alcohol Hydrogels
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acrylamide acrylate acrylic acid adsorption American Chemical Society anionic aqueous solutions associative thickeners ASTs behavior birefringence carboxyl groups cationic chain Chem coatings coil colloidal conformation copolymer copolymerization cross-linking cross-linking agent curdlan decrease degree of swelling dispersions effect emulsion ethoxylated excimer extensional fluid fluorescence formation formulations function HASE HEUR higher HMHEC hydrogels hydrophobic hydrophobic associations hydrophobic monomer hydrophobically modified increase initial interactions intermolecular intrinsic viscosity ionic ionization latex latices Macromolecules measurements methacrylate methacrylic acid micellar micelle modulus molecular weight molecules monomer NaCl nonionic surfactant observed obtained paint particles Patent Phys PLMA PMAA poly(acrylic acid polyelectrolytes polymer polymer concentration polymerization polysoap pyrene rheology salt samples shear rate shown in Figure sodium soluble solution properties solution viscosity solvent spectra spectrum stability strain rate structure studies surfactant synthesis temperature values water-soluble polymers