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amorphous amount atactic bonds brittle butyl rubber carbon atoms cellulose chain segments Chapter chemical containing corresponding crack cross-linked crystalline polymers crystalline rubber curve deﬁned deﬁnite deformation density diffraction diﬂiculties dimensions direction effect energy example extension ﬁbres ﬁgures ﬁlaments ﬁnal ﬁnd ﬁrst ﬁxed ﬂexible ﬂow force fracture freezing-point depression geometrical glassy polymers heat hence important increase inorganic glasses length liquid material measured mechanical properties melting modulus molecular weight natural rubber nylon observed obtained ordinary original osmotic pressure perspex physical properties plane polyethylene polymer molecule polymeric polypropylene polystyrene polythene pressure produced rate of crystallization rayon reﬂection relation repeating unit result rotation rubber elasticity rubber-like scientiﬁc shear stress shown in ﬁg signiﬁcant single crystal solid solution specimen strain strength stretched structure suﬂicient surface synthetic tensile stress Terylene theoretical theory tion transition unit cell unstrained vapour viscose rayon viscosity volume vulcanized rubber X-ray yarn