Electrode Kinetics |
Contents
POTENTIALDEPENDENT RATE CONSTANTS | 1 |
THE DISTRIBUTION OF POTENTIAL | 14 |
TECHNIQUES FOR MEASURING ELECTRODE REACTIONS | 47 |
Copyright | |
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a²c anion bulk calculated capacitance CDL,o CH₂ chemical cosh current-voltage curve cyclic voltammetry Debye length Debye-Hückel theory describes diffuse double layer diffuse layer distance drop E₁ effect electrochemical reaction electrochemistry electrode kinetics electrode reaction electrode surface electrolyte equilibrium fast Fe² Fe2+ Fe³ Fe3+ flux free energy function G₁ gradient H₂O Helmholtz layer Hence interface ionic atmosphere ions irreversible system k₁ k₂ measured mercury metal molecules Nernst equation nitrobenzene obtain oxidation polarography potential difference potential of zero pre-equilibrium proton proton transfer rate constant rate determining step react reactant reaction coordinate reaction layer reactions in solution reduction reversible ring electrode rotation speed shown in Fig shows single electron transfer sinh solvation solvation changes solvent species Tafel plot take place tanh term thermodynamics transition transport typical unit area values wave zero charge дс дх