Photoinitiated PolymerizationKevin D. Belfield, J. V. Crivello Photoinitiated Polymerization is divided into five sections. Free radical photopolymerizations command most of the interest and activity within the field and thus is discussed first. The second section discusses kinetic studies of the mechanism of free radical polymerizations. The third section covers cationic photopolymerizations, which along with free radical polymerizations, are being used in many industrial applications. The fourth section is devoted to recent developments in novel photopolymeriztion chemistry. This section describes new photobase generators, developments in monomers, oligomers and templated polymerizations of liquid crystal polymers. Finally, the fifth section portrays new and emerging applications for photopolymerizations. |
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Spectroscopic Investigation of ThreeComponent | 15 |
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2003 American Chemical absorption acrylate adhesion allyl amine benzophenone calixarene cationic photopolymerization cationic polymerization chain Chem coatings compounds concentration conversion copolymerization copolymers Crivello crosslinking cured films decrease diaryliodonium double bonds effect electron energy epoxy exotherm experimental Figure fluorescence fluorinated formulations free radical glass transition grafted amounts groups HDDA heat hydrogen bonding increase initiation irradiation kinetics lamp laser light intensity Macromolecules maleimide MDEA measured mechanism metallocene methacrylate mixture modulus molecular weight monomer MPDOX mW/cm² nitrogen obtained oligomers onium salt OX-SQ oxetane oxygen Photo-DSC photochemical photocuring photoinitiated cationic polymerization photoinitiator photolysis photopolymerization photosensitizers phthalimide polybutadiene Polym polymerization rate presence probe produced properties QA salt rate of polymerization reaction reactivity resin ring-opening sample Scheme sensitivity solution solvent spectra spectroscopy structure surface synthesis temperature thermal thiol-ene thiols transfer triplet two-photon UV-cured vinyl ether viscosity wavelength Wilkinson's catalyst