American Chemical Society, 2003 - Language Arts & Disciplines - 565 pages
Photoinitiated Polymerization is divided into five sections. Free radical photopolymerizations command most of the interest and activity within the field and thus is discussed first. The second section discusses kinetic studies of the mechanism of free radical polymerizations. The third section covers cationic photopolymerizations, which along with free radical polymerizations, are being used in many industrial applications. The fourth section is devoted to recent developments in novel photopolymeriztion chemistry. This section describes new photobase generators, developments in monomers, oligomers and templated polymerizations of liquid crystal polymers. Finally, the fifth section portrays new and emerging applications for photopolymerizations.
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Spectroscopic Investigation of ThreeComponent
A Mechanistic Description of the Sensitized NSubstituted
Photoinitiation of Acrylates via Sensitized Phthalimide
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2003 American Chemical absorption acrylate addition adhesion allyl American Chemical Society amine benzophenone calixarene cationic photopolymerization cationic polymerization chain Chem coatings compounds concentration conversion copolymerization copolymers Crivello crosslinking cured films curing decrease diaryliodonium double bonds effect electron energy epoxy exotherm experimental films fluorescence fluorinated formulations free radical glass transition glass transition temperature grafted amounts groups HDDA heat hydrogen bonding increase initiation irradiation kinetics lamp laser light intensity liquid Macromolecules maleimide MDEA measured mechanism metallocene methacrylate mixture modulus molecular weight monomer nitrogen obtained oligomers onium salt OX-SQ oxetane oxygen Photo-DSC photochemical photocuring photoinitiator photolysis photopolymerization photosensitizers plates polymer polymerization rate presence probe produced properties QA salt rate of polymerization reaction reactivity resin ring ring-opening sample Scheme sensitivity solution solvent spectra structure surface synthesis temperature thermal thiol-ene thiols transfer triplet two-photon UV-cured vinyl ether viscosity wavelength Wilkinson's catalyst