Principles and Applications of ESR Spectroscopy (Google eBook)
Springer Science & Business Media, Jan 4, 2011 - Analytical biochemistry - 474 pages
Principles and Applications of ESR Spectroscopy fills the gap between the detailed monographs in ESR spectroscopy and the general textbooks in molecular physics, physical chemistry, biochemistry or spectroscopy. The latter only briefly explain the underlying theory and do not provide details about applications, while the currently available ESR textbooks are primarily focused on the technique as such. This text is based upon the authors’ long experience of teaching the subject to a mixed audience, in the extreme case ranging from physics to biology. The potential of the method is illustrated with applications in fields such as molecular science, catalysis and environmental sciences, polymer and materials sciences, biochemistry and radiation chemistry/physics. Theoretical derivations have in general been omitted, as they have been presented repeatedly in previous works. The necessary theory is instead illustrated by practical examples from the literature.
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2 MultiResonance and Pulsed ESR
3 Analysis of Spectra
4 MultiFrequency and High Field ESR
Part II Applications of ESR
5 Applications to Molecular Science
6 Applications to Catalysis and Environmental Science
American Chemical Society analysis anatase anisotropic anisotropic hyperfine applied atoms axes axial axis bi-radical calculated cation chain Chapter Chem complex computed dose electron spin ENDOR ENDOR spectra ESEEM ESR spectra ESR studies experimental figure is adapted free radicals g-factor g-tensor hf splittings hydrogen hyperfine coupling hyperfine coupling tensor hyperfine splitting hyperfine structure HYSCORE intensity interaction irradiated isotropic line shape line width Lund magnetic field matrix measurements method microwave frequency molecular motion molecules nuclear spin nuclear Zeeman nuclei observed obtained orbital orientation paramagnetic species permission peroxy radicals Phys polymer powder principal values procedure pulsed ESR quantum number radiation radical anions radical pairs reaction resonance rotation sample Shiotani shown in Fig signal simulation single crystal solid spectroscopy spectrum spin density spin label symmetry temperature tensor Ti3+ TiO2 transition metal transition metal ions trapped triplet unpaired electron X-band zeolite zero-field splitting