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absorption Amsterdam analysis approximate argon atomic beam autoionizing BARIUM broadening calculated cell cesium coefficients collisions components configuration interaction constant cross section decay density detected determined detuning diamagnetic dipole dye laser electric field electron emission energy levels excitation experiment field strength fluorescence frequency Hartree-Fock hydrogen hyperfine structure Institute of Physics intensity investigated ionisation ionization ions isotope isotope shift J.E. Hansen laser beam laser light laser spectroscopy Lett magnetic field Marburg MCHF measured metastable method molecular molecules neon observed obtained optical oscillator strengths parameters perturbation photon Phys plasma polarization potential pressure probe beam pulse pumping quadrupole quantum defect quantum numbers radiation ratio region resonance Rydberg Rydberg atoms signal spectra spectral lines spectrum splitting Stark effect Table technique theoretical theory thermal lens transition probabilities trap Universitat values vapour wave functions wavefunctions wavelength width Zeeman