Spectroscopic Properties of Rare Earths |
Contents
The Rare Earths | 1 |
Energy Levels of Rare Earth Atoms and lons | 8 |
Intensities in Rare Earth Spectra | 83 |
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actinides additional angular application approximately associated atomic becomes calculated charge Chem closed cm-¹ complete components configuration configuration interaction consider considerable constant contain core correction corresponding coupling scheme crystal field deduced defined detailed determined diagonal effects eigenfunctions electron electrostatic interaction energy levels equation evaluated example experimental factors follow free ion give given ground hence hyperfine structure intensities interaction intermediate coupling irreducible representations isotope shifts J₁ J₁j coupling J₂ lanthanides limit line strengths LS coupling magnetic magnetic field matrix elements measured method multiplet normal nuclear observed obtain occur operator parameters particular Phys possible potential properties pure quantum numbers radial integrals rare earth reduced relative relativistic result selection rules separation shell shown simple spectra spin-orbit interaction splittings studied symmetry Table theory transformation transitions usually values wave functions whereas yield Zeeman