Interfacial Electrochemistry: An Experimental Approach |
Contents
SOME THEORETICAL CONSIDERATIONS | 1 |
viii | 43 |
Evaluation of Kinetic Parameters | 60 |
Copyright | |
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adsorbed adsorbed intermediates adsorption anodic anodic and cathodic applied battery benzene bulk calculated capacitance capacitor capillary Chem chemical concentration corr corrosion counter electrode coverage current density curve decrease depends determined double-layer drop Electrical Setup electrocapillary Electrochemistry electrode reactions electrode surface Electrodes and Electrical electrolyte electrosorption equilibrium exchange-current density experiment experimental faradaic free energy Frumkin fuel cells function of potential galvanostatic Gileadi given H₂O Helmholtz hydrogen hydrogen-evolution reaction input interphase ionic ions isotherm kinetic parameters layer linear measured mercury metal nitrogen obtained operational amplifier oscilloscope output overpotential oxidation oxygen oxygen evolution platinum plot polarization Polarography potential difference potential of zero potentiostat pretreatment rate-determining step reactant reaction order reaction takes place reference electrode region resistance reversible potential shown in Fig solution solvent species steady-state sweep rate Tafel slope transient Treatment of Results Volt voltage water molecules zero charge ᎡᎢ