Advances in Organometallic Chemistry: Multiply Bonded Main Group Metals and MetalloidsThis widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry--the study of compounds containing carbon metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. In basic research, organometallics have contributed inter alia to:
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Contents
Chapter 2 The Chemistry of Silenes | 71 |
Chapter 3 Iminosilanes and Related CompoundsSynthesis and Reactions | 159 |
Chapter 4 SiliconPhosphorus and SiliconArsenic Multiple Bonds | 193 |
Chapter 5 Chemistry of Stable Disilenes | 231 |
Chapter 6 Stable Doubly Bonded Compounds of Germanium and Tin | 275 |
Arsenic Antimony and Bismuth | 325 |
Chapter 8 BoronCarbon Multiple Bonds | 355 |
| 393 | |
| 409 | |
Cumulative lndex for Volumes 3739 | 413 |
Common terms and phrases
2,4,6-trimethylphenyl addition adduct aluminum analog Angew aromatic aryl Auner bond angles bond length boron bulky carbonyl CH3 CH3 Chem chemical shifts Chemistry CMe3 complexes compounds coordination Couret cycloaddition delocalization derivatives diene digermenes dimer disilenes double bond Driess electron electronegativity ene reaction Engl Escudié fluorenylidene formation formed gallium geometry germanimines germanium group 3 element heavier main group iminosilane indium Inorg involving Ishikawa isomeric isomers kcal kcal mol ligands lone pair Me3Si Michl molecule multiple bonding nitrogen observed orbital Organomet Organometallics Organometallics 1992 p-orbital Ph Ph Ph phosphasilenes phosphorus photolysis planar plane react reaction reactivity reagents rearrangement ring rotation Satgé Scheme shorter shown in Eq Si=P silenes silicon atom silicon-carbon double bond silylene SiMe3 single bond species spectroscopy stable silenes steric substituents synthesis T-bonding t-Bu T-overlap Table temperature thermal thermolysis three-coordinate tion torsion angle trapping undergo Wiberg yield