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absorption lines accurate Appendix approximately Arrhenius atoms attenuation and boundary Baulch Boltzmann distributions boundary layer effects calculated carbon monoxide combustion constraints data reduction deBoer and Miller detector determined divisions divs emission experiments emission system equations error estimated experimental expression factor formation experiments formation profile gases initial conditions InSb isentropic kinetics LAB TIME microseconds laser absorption experiments laser absorption system laser absorption technique least-squares fit listed in Table measured minimized mole fraction molecules NASA-Lewis program nitric oxide nitrogen nitrogen dioxide obtained optical cavity optimal oscillogram oscilloscope voltage parameters plot post-shock present data present study presented in Fig pressure radiation rate coefficient relaxation rate scope mV shock attenuation shock front shock speed shock tube shock wave shock-tube signal slope Table III.l temperature temperature range theoretical tion Typical NO formation upward curvature vibrational energy vibrational level vibrational non-equilibrium vibrational relaxation experiments vibrational temperature yields Zeldovich reactions