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Experimental Thermoanalytical Techniques
Chapter3 HexamminecobaltIII Complexes
19 other sections not shown
Ablov amine ammine complexes ammonia ammonium chloride anhydrous anion ature Biltz cadmium(II Chem chloride complex chromium(III cobalt(II color changes composition compound began contained coordination copper(II corresponded curve inflection deamination deamination reaction deaquation reaction decomposed decomposition diammine Differential thermal analysis dissociation pressure dissociation products dissociation temperatures DTA curves endothermic peaks ethylenediamine evolution of ammonia exothermic formation formed furnace given in Fig halide heating rate helium hexammine higher temperatures Inorg intermediate compounds investigated iodide kcal latter compound ligand Lobanov lose mass loss magnetic susceptibility manganese(II mass-loss curves matrix mole mole of complex mole of ethylenediamine moles of ammonia Mori nickel(II nitrogen Nucl observed obtained oxidation platinum platinum(II pyridine pyrolysis residue rhodium(III scandium(III shown in Fig similar stoichiometry studied the thermal sulfate Temp temperature range TGA curves thermal analysis curves thermal dissociation reaction thermal stability thermoanalytical thermoanalytical techniques transition triammine type complexes vacuo W. W. Wendlandt zinc(II