Introduction to Molecular Structure and Spectroscopy
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Absorption and Emission of Radiation
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absorption angular momentum antisymmetric approximate assumed atomic orbitals atoms axes axis band bond Calculate chemical shift components coordinates corresponding derived diagram diatomic molecule doubly degenerate effect electric dipole electric field electronic configuration electronic transition emission energy levels equation equivalent example excited experimental external field external magnetic field first-order fluorescence frequency given ground electronic hyperfine hyperfine coupling hyperfine splitting infrared integral intensity interaction internuclear irreducible representations laser magnetic dipole magnetic field magnetic moment matrix microwave MO's molecular motion multiplet normal modes nuclear spin nuclei observed obtain occur orbital oscillator paramagnetic perpendicular planar plane point group polarizability polarization polyatomic molecules prolate protons quantum number radiation Raman relatively resonance result rotation-vibration rotational selection rules shown in Figure species spectra spectroscopy spectrum splitting Stark effect structure symmetric top symmetry operations term symbol tion totally symmetric transformation valence vector vibrational modes vibronic wavefunctions Zeeman zero