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accumulates acetaldehyde acetate acetoacetate acetoacetyl acetoacetyl-SCoA acetone acetyl phosphate acetyl-SCoA acidi-urici active alanine alcohol allantoin amino acids ammonia anaerobic bacteria Bacteriol Biochem Biol butanol butyrate synthesis butyric acid butyric acid bacteria butyric acid fermentation butyryl phosphate butyryl-SCoA carbon atoms carbon dioxide carbon dioxide reduction carbon monoxide carboxyl catalyzed cell-free extracts cells cellulose CH3CH2CH2COOH CH3COOH CH3COOPO3H2 Chem chemistry citramalate Clostridium kluyveri coenzyme converted COOH crotonyl-SCoA decom decomposed derived from carbon DPNH enrichment cultures enzymatic enzyme equation ethanol evidence extracts of Cl fatty acids fermentation formiminoglutamate formiminoglycine glutamate glycine H. A. Barker histidine HSCoA hydrogen intermediate involves isolated kluyveri extracts lactate Mbact mesaconate methane bacteria methane formation Methanobacterium methyl group mole of carbon nitrogenous compounds observed obtained omelianskii organism orotic acid oxidation pathway phosphotransacetylase propionate propionicum pure cultures purine purine fermentation pyruvate SCoA serine shown species of methane Stadtman studied substrates tetanomorphum threonine tion uric acid vinylacetate xanthine