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absorption spectrum analysis argon array atomic beam autoionising barium beam-foil broadening and shift calculations collisional collisions configuration interaction continuum cross section curve decay density detection determined dipole discharge dye laser effects electric field electron energy levels excitation experiment experimental Figure fluorescence frequency Hartree-Fock high resolution hollow cathode hyperfine splitting hyperfine structure intensity ionic ionisation ionization ions isoelectronic isotope isotope shift laser beam laser pumped laser spectroscopy Lett lifetimes lines magnetic field measurements method neon neutral noble gas Nucl observed obtained optical orbital oscillator strengths parameters peaks perturbed photon Phys plasma polarisation polarization pressure pulse pumped quadrupole quantum beats quantum defect quantum numbers radiation radiative region relativistic resonance Rydberg atoms Rydberg series Schmoranzer selfalignment sequence signal spectra Stark Stark Effect Table technique thallium theoretical theory transition probabilities trap values vapour wave functions wavelength width Zeeman