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absorption spectrum analysis argon array atomic beam autoionisation barium beam-foil broadening and shift calculations collisional collisions configuration interaction continuum cross sections curve decay density detection determined discharge dye laser effects electric field electron energy levels excitation experiment field strength Figure fluorescence frequency Hartree-Fock high resolution hollow cathode hyperfine splitting hyperfine structure intensity investigated ionic ionisation ionization ions isoelectronic isotope shift isotopes laser beam laser pumped laser spectroscopy Lett lifetimes lines magnetic field measurements method molecular neon neutral noble gas observed obtained optical orbital oscillator strengths parameters peaks perturbed photon Phys plasma polarisation polarization pressure pulse pumped quadrupole quantum beats quantum defect quantum numbers radiation radiative region relativistic resonance Rydberg atoms Rydberg series signal spectra spectrometer splitting Stark Stark Effect Table technique thallium theoretical theory transition probabilities trap values vapour wave functions wavelength width Zeeman