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aryl vinyl polymers blend composition blend miscibility blend morphology blend systems C.W. Macromolecules 1982 calculated Chapter chromophore corr curve differential scanning calorimetry dimensional EFS concentration enthalpic interactions equilibrium equilibrium thermodynamics excimer decay excimer fluorescence excimer forming sites exciton experimental fictive Fitzgibbon fluorescent polymer Fox equation function of blend function of host Gashgari guest polymer homologous series host matrix host polymer solubility Ie/Im immiscibility increase infinite molecular weight intermolecular EFS measured miscible blend model compound molecular weight monomer decay monomer fluorescence naphthalene nearest neighbor transport optical clarity P2VN concentration P2VN-Py P2VN/PCMA blend parameter model PCMA PEMA phase separated blends phase separation photophysical model photostationary Phys PiBoMA PiPMA PMMA PMMA(H PnBMA PnPMA poly(alkyl methacrylates polymer blend polymer coils polymer concentration polymer solubility parameter pyrene quantum yields random walk ratio Semerak shown in Figure solvent ternary thermodynamics toluene trap