Modern Phosphonate ChemistryA century after their discovery, phosphonates have become important compounds recognized both for their use as efficient reagents in organic synthesis and for their biological and industrial importance. This unique, up-to-date reference presents a concise summary of the state of the art in phosphonate chemistry, covering the role of phosphonates in |
Contents
1 | |
Chapter 2 The Silylphosphonates | 31 |
Chapter 3 The Halogenophosphonates | 59 |
Chapter 4 The Epoxyphosphonates | 139 |
Chapter 5 The Formylphosphonates | 183 |
Chapter 6 The Cyanophosphonates | 249 |
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Common terms and phrases
Abstr acetals active acyl addition Akad alcohol aldehydes alkyl allyl analogues application approach base bond Bull carbanions carbon carbonyl catalytic Chem chemistry Chim chlorides Commun compounds containing converted corresponding cyclization derivatives dialkyl diethyl effect efficient electrophilic enol esters ethyl fluorination followed formation formed functionalized give hydrogen hydrolysis inhibitors intermediate involves isolated ketones Khim MeOH method Michaelis–Arbuzov mixture n-BuLi Nauk SSSR nitriles novel nucleophilic Obshch obtained oxidation P(OEt Patent Appl Perkin Trans phonates phosphite phosphonic acids phosphonylated phosphorus preparation presence procedure provides Pudovik reaction reactivity reagents rearrangement reduction reflux Relat reported resulting ring room temperature route salt Savignac Scheme selective Silicon sodium stereoselective structure studies substituted Sulfur Synth synthesis synthetic Tetrahedron Lett Transl treatment trialkyl phosphites triethyl phosphite undergo USSR Engl vinyl yields