14 pages matching tetrahedral interstices in this book
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13C nuclei 13C relaxation rates a-phase activation energies activation enthalpy adiabatic Arrhenius atoms behaviour calculated Chapt Chem chemical shift contribution coordination sphere correlation corresponding coupling constant Debye frequency deduced diffusion coefficient dipolar DMF molecules DMSO effect enthalpy exchange rates experimental results Fe(ClO4)3 in DMF FeCl3 FeCl3/DMF solutions formyl group formyl nuclei full line Gorski Gorski-effect Gorski-effect data gyromagnetic ratio H. G. Hertz Hertz high temperatures hydride phases hydrogen diffusion hydrogen nuclei incoherent tunnelling increase investigated jump frequencies kJ/mol l/TlA lattice low temperatures magnetic field measurements metals methyl groups methyl nuclei Nb'H niobium observed obtained octahedral octahedral interstices paramagnetic parameters perchlorate Phys pre-exponential factor proton diffusivity proton relaxation rates ratio resonance sample Sect solutions of Fe(ClO4)3 solvation sphere solvent solvent molecules spin-lattice relaxation rate spin-spin relaxation technique Temperature dependence temperature range tetrahedral interstices transverse relaxation rates trapping tritons values