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absorption absorption spectrum Anex anharmonic band bolometer bond lengths bound C-H stretching C-H frequency C-H motions C-H stretching frequency C-H stretching vibration C-H vibration cavity chemical bond cyclic trimer dimer and trimer dimer frequencies electron correlation electrostatic model Ewing F-center Figure force constants force field free C-H stretching frequency mode G. E. J. Chem gas phase H C N harmonic HCN bend HCN molecule higher polymers hydrogen bond hydrogen cyanide hydrogen cyanide clusters infrared initio calculations intermolecular Laser frequency linear HCN linear polymer linear trimer matrix isolated molecular beam monomer monomer HCN normal coordinate analysis normal mode analysis observed shift perturbation Phvs potential energy distribution predicted quantum number red-shift scan SCF calculations solid solid-like spectroscopy of hydrogen stagnation pressure stretching motion tetramer tional transitions trimer feature vibrational energy shifts vibrational frequency shifts vibrational levels vibrational overtones vibrational spectroscopy vibrationally excited