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average behavior breakup calculated chain Chem coefficient concentration constant constitutive equation curve decrease deformation dependence dimensionless dispersed Doi-Edwards drop droplet dynamic effect elastic elastomer emulsions entanglement equation equilibrium experimental data experiments extensional viscosity fiber Fluid Mech force frequency function gelation gels glycerol helix increase instability interaction interfacial linear viscoelastic matrix measured mechanical mesa modulus molecular weight molecules morphology nematic Newtonian Newtonian fluids Non-Newtonian Fluid normal stress observed obtained orientation parameters particles PDMS phase inversion Phys plateau plotted polydispersity polymer polymer blends polymeric predictions properties range relaxation reptation Rheol rheometer samples scale shear flow shear rate shear stress shear thickening shear thinning shear viscosity shown in Fig shows simple shear simulations Society of Rheology solutions solvent steady shear steady-state strain structure surface suspensions temperature tensor theory Tikhonov regularization torque transient uniaxial values velocity viscoelastic viscometry volume fraction yield stress