Advances in Strained and Interesting Organic Molecules, Volume 7B. Halton This work provides timely essays on the many facets of strained and interesting organic molecules. Contributions from experts in the field provide insights not only for the practicing organic chemist, but also for the student at the senior undergraduate and graduate level. |
Contents
STRUCTURES OF BENZENE DERIVATIVES WITH | 43 |
ALLCARBON MOLECULES FROM SMALLRING | 153 |
RELATIVE STABILITIES OF ISOMERIC FULLERENES | 185 |
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1.1]paracyclophane 4]paracyclophane absorption acceptor Achiba alkene Angew angles anions aromatic averaged C-C bond benzene ring Bickelhaupt boat forms bond lengths bridgehead carbon atoms C-C bond length C₂ cages calculations carbon clusters Chem chemical shifts chemical trapping Chemistry CO₂Me compounds computations corresponding cumulene cyclo[n]carbons cyclophanes cycloreversion deprotonated Dewar benzene Diederich distorted donor electronic Engl experimental Figure formation fullerene geometry hydrogen bonds initio intermediate intramolecular hydrogen bonds IPR Set IPR structures irradiation isolated isomerization isomers Kawashima kcal/mol kinetically stabilized kJ/mol mixture molecular molecules NC CN nitro group NO2 NO2 NO2 O₂N O₂N NO2 observed Okazaki optimized Osawa oxirane pentacoordinate Peterson reaction Ph Ph photochemical Phys planar polyyne precursors proton quantum chemical reactive resonance form SAM1 semiempirical shown in Scheme Slanina species spectra spectroscopic steric steric strain substituents symmetry synthesis Tetrahedron Lett topological twist forms Wittig reaction Wolff X-ray ylides