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AC noise antibody antigen applied voltage assay background noise biomedical analyses buffer solution capillary column capillary flow cell capillary tubing Chem chiral competitive binding competitive immunoassay complex concentration convective flow coumarin d,l-dansyl amino acids dansyl amino acids detection limit diameter drill bit electronic excited electroosmotic flow enantiomers energy ferrule flowing droplet fluorescence immunoassay fluorescent molecules fluoroimmunoassay fluorometry fluorophore He-Cd laser high pressure high voltage capillary high voltage electrophoresis HPLC human IgG induced fluorescence detection injection injector labeled IgG laser beam laser induced fluorescence liquid chromatography long-lived fluorescence signal lowest vibrational levels measurement microbore columns microbore HPLC molecules on-column optical optical fiber packing material phosphorescence photomultiplier photomultiplier tube photon counting pump quantum yield quencher quenching reservoir scattered light sensitive serum sample solvent spontaneous emission structure Tb chelate teflon teflon tubing temperature gradient terbium theoretical plates theoretical plates number triplet typical unlabeled antigen voltage capillary electrophoresis zeta potential