## Effects of Lattice Vibrations on the Optical Spectra of Ions in Crystals |

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### Contents

The general nature of vibronic interactions | 1 |

3lO Temperature dependence of the linewidths of four strong | 3 |

Highresolution trace of the nophonon line of | 5 |

9 other sections not shown

### Common terms and phrases

2g g absorption antisymmetric Appendix apply approximately assume band broadening calculation Chapter complex corresponds crystal field theory crystalline field cubic field d+ d+ define dx dy dz electric dipole transitions emission energy level diagram energy levels Enhancetron equation equilibrium experimental fluorescence frequency Gaussian ground Hamiltonian heat equation heater input involved Jahn-Teller effect lattice lg 2g lifetime linear combination linewidth lock-in amplifier look Lorentzian manganin manifold matrix elements measurements mode no-phonon line observed occur octahedral odd vibrations optical orbital parameters perturbation phonon phonon field photomultiplier polarization quantized scans second order Section shown in Fig signal simple singlet solutions spectral spectral lines spectrum spin spin-orbit coupling spin-orbit interaction spin-orbit splitting square wave symmetry temperature modulation tetragonal tetragonal distortion theoretical thermal tion traces transforms transition probability trigonal trigonal field values vibronic interactions wave functions widths xz yz