The Surface Chemistry of SoilsDescribes the surface phenomena in soils, both experiment and theory, from the point of view of modern coordinational chemistry. The topics covered include surface area and change, the structure of absorbed water, the points of zero change, electrokinetic phenomena, adsorption of inorganic and organic solutes, computer models of adsorption, a nd colloidal aspects of surface chemistry in soils |
Contents
THE REACTIVE SOLID SURFACES IN SOILS | 1 |
CHEMICAL MODELS OF SURFACE COMPLEXATION | 5 |
THE STRUCTURE OF WATER NEAR CLAY MINERAL SURFACES | 51 |
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adsorbed adsorbed water adsorption anion aqueous solution phase basal plane Ca2+ cation Chem chemical Clay Minerals clay particles coefficient Colloid Colloid Interface Sci concentration DDL theory diffraction electric electrolyte electrolyte solution electron equation equilibrium constants exchangeable cation experimental functional groups goethite hydrate hydrogen bonds hydrous oxide hydroxyl groups inner potential inner-sphere complex inner-sphere surface complexes interactions interfacial region interlayer ions isomorphic substitution kaolinite Lewis acid ligand measured metal cations molecular moles monolayer montmorillonite Na-montmorillonite octahedral sheet outer-sphere surface complexes oxide oxyanion parameters pH value phyllosilicate plane of shear primary solvation shell properties proton PZNC PZNPC PZSE quasicrystal reaction siloxane ditrigonal cavities siloxane surface smectite soil clay soil particle Soil Sci soil solution solid phase solvation shell specific surface area structure surface charge surface charge density surface functional groups suspension Table thermodynamic triple layer model vermiculite Waals water molecules X-ray