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General Features and Characteristics of Nonaqueous Solvents
Correlation of Properties in Different Solvents
17 other sections not shown
acetic acid acetone acetonitrile acid-base reactions acids and bases activity coefficients alcohols alkali-metal Amer American Chemical Society ammonia amphiprotic anions aprotic solvents aqueous solutions association basic behavior benzene Br0nsted calculated cations cell Chem Chemistry chloride complex concentration conductance Copyright determined dielectric constant different solvents dipolar aprotic solvents dipole dissociation constants DMSO donor electrolytes enthalpies of transfer entropies equation example formamide formation free energies halides hydrogen bonds increase infinite dilution iodide ion pairs ionic ionization kcal kcal mol-1 Kolthoff liquid ammonia lithium log m7H measurements medium effects metal methanol mixtures molal nonaqueous solvents obtained organic solvents osmotic coefficients partial molal volumes perchlorate Phys plot polarizable properties propylene carbonate protic proton Reprinted with permission salts scale single ions solubility solvation energy solvent molecules species standard potentials structure sulfolane temperature thermodynamic titration transfer activity coefficients transfer free energies transference numbers values vapor pressure