Nonaqueous Solution ChemistryProvides a concise, yet comprehensive source of information on the chemistry of solvents other than water. Emphasizes modern literature and answers to practical questions. Includes extensive tabulation and graphical representation of data on nonaqueous solution. |
Contents
General Features | 33 |
General Features and Characteristics of Nonaqueous Solvents | 34 |
Thermodynamic Properties | 77 |
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acetic acid acetone acetonitrile acids and bases activity coefficients alcohols alkali-metal Amer American Chemical Society ammonia amphiprotic anions aprotic solvents aqueous solutions association basic behavior benzene Brønsted calculated cations cell Chem Chemistry chloride complex concentration conductance Copyright Debye-Hückel determined dielectric constant dipolar aprotic solvents dipole dissociation constants DMSO electrode potentials electrolytes enthalpies of transfer entropies equation example formamide formation free energies H₂O halides hydrogen bonds increase iodide ion pairs ionic ionization kcal kcal mol-1 Kolthoff LiCl liquid ammonia lithium log mYH measurements medium effects metal methanol mixtures molal nonaqueous solvents obtained organic solvents osmotic coefficients partial molal volumes perchlorate Phys plot polarizable propylene carbonate protic proton Reprinted with permission salts scale single ions soln solubility solvation energy solvent molecules species standard potentials structure sulfolane temperature thermodynamic titration transfer activity coefficients transfer free energies transference numbers values ΔΗ