Electrochemical Systems |
Contents
Introduction | 1 |
Part A Thermodynamics of Electrochemical Cells | 27 |
Transport processes in junction regions | 42 |
Copyright | |
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activity coefficients anodic applied average binary electrolyte boundary conditions bulk solution calculated calomel electrode cathodic cation cell potential charge density chemical chloride cm²/sec coefficient of species composition concentration overpotential concentration variations constant current density current distribution depends difference diffusion coefficient diffusion layer dilute solutions dimensionless disk electrode distance double layer elec electric field electric potential electrochemical potential electrochemical systems Electrochemistry electrode reaction electrode surface electrolyte electrolytic solution electroneutrality equilibrium exchange current density expressed Faraday's constant Figure fluid flux free convection gradient H₂O interface ions John Newman laminar Laplace's equation limiting current liquid junction liquid-junction potentials mass transfer mass-transfer measured mercury drop metal molar number of species Nusselt ohmic potential drop overpotential phase pressure problem Pt(s reactant reference electrode rotating disk Schmidt number solvent sulfate supporting electrolyte surface overpotential temperature thermodynamic tion transference number transport properties velocity profile zero