Introduction to Ligand Field Theory"I have tried to give an introduction to that field of chemistry which deals wit the spectral and magnetic features of inorganic complexes. It has been my intention not to follow the theory in all its manifestations, but merely to describe the basic ideas and applications. This has been done with an eye constantly aimed at the practical and experimental features of the chemistry of the complex ions. The book is thus primarily intended for the inorganic chemist, but it is true that, in order to follow the exposition, a course in basic quantum mechanics is needed"--Preface. |
Contents
Preface | 1 |
2a Orbitals and states | 7 |
2e Twoelectron operators | 17 |
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A. D. Liehr A₁ absorption bands absorption spectrum Acta Chem atom axis bonding C. J. Ballhausen C. K. Jørgensen calculation Chem cm-¹ complexes component compound crystal field theory crystalline field cubic d₂ degeneracy degenerate diamagnetic dipole distortion double group electronic configuration electronic structure energy example excited Faraday Soc g factor given ground Hamiltonian Hence interaction irreducible representations J. H. Van Vleck Jahn-Teller Jahn-Teller effect Japan L. E. Orgel ligand field theory linear combinations London M. H. L. Pryce magnetic susceptibility matrix elements Moffitt molecular orbitals molecule Ni(II obtained paramagnetic paramagnetic resonance parameters perturbation Phys physik point group potential Proc quantum number rotation singlet spectra spin spin-orbit coupling splitting strong-field Sugano symmetry operations T₁ T₂ Table temperature term tetragonal tetrahedral tion transform transition trigonal field wave functions weak-field zero Φι