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FORMAL KINETICS OF DOUBLEBOND POLYMERISATION
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active centres Amer atoms average molecular weight calculated cent chain length chapter Chem chemical component concentration condensation cross-linking crystal crystalline curve deformation dilute solutions dipole distribution divinyl effect end-group energy of dilution entropy of mixing equal equation equilibrium experimental extrapolation Faraday Soc fibre Flory follows frequencies function Gibbs free energy give given groups heat of dilution heat of mixing high polymers increases independent inhibitor initial interaction internal energy kinetic lattice linear polymers liquid measured method methyl mixture mole fraction molecules monomer nitrocellulose number average number of molecules obtained occurs osmotic pressure phase plasticiser plot polymer chain polymer molecules polymer solutions polymerisation polystyrene polyvinyl acetate possible properties random rate constant ratio reaction relaxation rotation rubber simple solvent specific viscosity structure temperature termination theoretical theory thermodynamic total number usually vapour pressure vibration vinyl viscosity volume fraction vulcanised X-ray zero