Linear Polymers |
Contents
THE STRUCTURE OF HIGH POLYMERS | 1 |
DOUBLEBOND POLYMERISATION | 61 |
FORMAL KINETICS OF DOUBLEBOND POLYMERISATION | 68 |
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Common terms and phrases
active centres Amer amorphous polymers average molecular weight calculated cent CHâ‚‚ chain length chapter Chem chemical components concentration constant cross-linking crystalline curves deformation diffusion dilute solutions dipole distribution effect end-group energy of dilution entropy of mixing equal equation equilibrium experimental experiments extension extrapolation Faraday Soc Flory function Gibbs free energy given gives heat of mixing high elasticity Huggins increase independent interaction kinetic lattice linear polymers measured method mixture molar volume mole fraction molecules monomer nitrocellulose number average obtained occurs osmotic pressure partial molar phase plasticiser plot polymer chain polymer molecules polymer solutions polymerisation polystyrene polyvinyl acetate properties random random coil Raoult's law ratio reaction relaxation rotation rubber scattered sedimentation shear solvent solvent molecules specific viscosity stress structure temperature tension theoretical theory thermodynamic total number transition usually vapour pressure viscosity volume fraction vulcanised zero