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ELECTROCHEMICAL BEHAVIOR OF THE LIGANDS
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6,7-Dichloro-5,8-quinolinequinone acetate-acetic acid buffer Acid Dissociation Constants acid solutions adsorbed adsorption anodic buffer solution cathodic peak current cell Chem chemical cobalt complex compounds coordination coulometry curve Cyclic Voltammetric Data cyclic voltammograms decrease diffusion current dissociation constant DMSO DMSO-water solvent drop mercury electrode EE mechanism electrochemistry electrolysis electron transfer electron transfer reactions Epp/2 and AEp equation expected formation constants half-wave potential hydroquinone hydroxy ia/ic increase ion present minus lead ion lead nitrate ligand mercury electrode area metal ion concentration metal salts minus the half-wave mV vs SCE n-value nickel nitrate nitrate concentration nitrogen observed oxidation parameter peak current function peak potential perchloric acid phenanthroline polarographic potentiostat Presence of Metal protonation protonation reactions quinolinequinone quinone radical anion rate of voltage ratio scan rate second wave similar sodium hydroxide species standard potentials TABLE theoretical triethanolamine buffer V/sec values of Epp/2 voltage scan zinc zinc nitrate