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FurtHer Discussion of EnsemBles
General Relations for Independent DistinguisHaBle
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adsorbed adsorbed molecules adsorption approximation assumed atoms average Bose-Einstein Bragg-Williams calculate canonical ensemble Chapter Chem chemical potential classical statistics component configuration consider constant coordinates corresponding crystal curve deduce degrees of freedom density Derive dilute discussion electronic energy levels entropy equilibrium example experimental Fermi-Dirac free energy frequency gases grand partition function heat capacity Hence ideal gas independent integral interaction intermolecular forces ions isothermal lattice gas limit linear liquid macroscopic Mayer microcanonical ensemble molecular monatomic nearest-neighbor notation number of molecules obtain one-component one-dimensional pair particles Phys polyatomic polyelectrolyte polymer polymer molecules potential energy pressure probability Problem properties quantum quantum-mechanical radial distribution function reaction rotation second virial coefficient Section solute molecules solvent statistical mechanics statistical-mechanical subsystems surface symmetry term theory thermodynamic equation thermodynamic functions tion variables vibrational virial coefficient virial expansion volume Waals zero