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absorption spectra Accepted in revised Acta aliphatic analysis aqueous arc current aromatic assigned atom band benzodiazepines Boltzmann Brock University C-NMR calculated Canada carbazole carbon carboxyl Carleton University Cataliotti CF3C chain charge transfer Chem chemical shifts cnr1 coals coefficient complexes compounds concentration coumarin crystal Department of Chemistry deuterated diazepam double bond doublet effect electronic emission Er/X ethanol Ítre experimental Figure fluorescence frequency glutamic acid hydroxyl group increase infrared intensity interaction journal keto ketoconazole ligand lignite medazepam methoxyl mixture mode molecular molecules Montreal observed obtained Ontario Ottawa oxazepam oxazepam and medazepam Paliani peak peat photophysical Phys plant material plasma polar proton Quebec Raman spectra ratio red-shift region resonance samples Schiff base solid solid-state solutions solvents spec Spectrochim spectrometer Spectrosc Spectroscopy spectrum splittings St Catharines stretching studied symmetry Table temperature tion transition unit cell v(CS values vibrational wavenumbers