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Ligand or Crystal Fields
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Abragam absorption angular momentum arises atomic hydrogen axial axis behavior CaF2 calculation Chapter Chem components configuration consider coordinate system cos2 coupling crystal field cubic axes cubic symmetry degeneracy described discussed doublet effect electric field electron paramagnetic resonance energy levels EPR transition equations frequency g factor ground manifold Hamiltonian of Eq hyperfine interaction hyperfine structure impurity intensity interstitial isotropic Jahn-Teller effect Larmor frequency lattice magnetic dipole magnetic field magnetic resonance matrix elements microwave molecular orbital molecule ion negative charges nuclear magnetic nuclear spin nuclei observed obtain occur oscillating paramagnetic entities parameters perturbation theory phonon Phys plane polarization population principal quadratic quantum numbers rare-earth relaxation rate result rotating saturation Section shown in Fig signal Solid spectra spectrum spherical spin Hamiltonian spin-lattice relaxation spin-orbit interaction splitting stress temperature tensor tetragonal thermal equilibrium tonian transition-group usually vector wave function York Zeeman interaction zero