Initiation precursors and initiators in laser-induced copolymerization of styrene and maleic anhydride in acetone
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absorbance of acetone Absorbance versus mole absorption band acetonitrile argon ion laser Barton Candela dye laser chloroform Christopher Newport copolymer is proposed CTC's diradicals electron-donating solvents exciplex Gilda I0 normalized initiate polymerization initiating precursor initiating species initiation step Initiators in Laser-Induced intermediate reactions lead investigated at 365 ion laser operating irradiation iV-dimethylformamide Ken Chang Langley Research Center laser experiments Laser-Induced Copolymerization LUMO MA/acetone maleic anhydride Meador measurements at 365 mechanism Miner and Willard mol.L mol.L-1 Sty/MA Molar absorptivity molecular orbital molecule NASA paper suggest intermediate Performing Organization photoinitiation step photon plex polymer Precursors and Initiators produce a monoradical propagation pulsed Candela pulsed laser Radical Ion rate of polymerization Sadhir sole absorbing species solu sorbing sorption spectra spectrophotometer Sty/acetone Sty/MA complex absorption Sty/MA/acetone solution Styrene and Maleic styrene/maleic anhydride charge-transfer styrene/maleic anhydride copolymer suggest intermediate reactions termination tion triplet ultraviolet UV mode versus M2 wavelengths