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alloys anisotropy annealing antiferromagnetic applied field approximation atoms axis band behavior calculated Chem compounds constant coupling crystal field Curie Curie point Curie temperature curve decrease density determined discussed domain domain wall effect electron energy equation exchange interaction exciton experimental Fermi ferrite ferromagnetic films frequency function Hamiltonian Hubbard model hyperfine hyperfine field impurity increase indicate ions lattice layers linear low temperature magnetic field magnetic properties magnetic susceptibility magnetostriction magnon materials measurements metals molecular field neutron observed obtained orbital paramagnetic parameters particles peak phase phonon Phys plane polarization Proc range rare earth ratio region room temperature rotation sample saturation saturation magnetization scattering shown in Fig single crystal slave tape solid specific heat spectra spectrum spin splitting structure sublattice surface susceptibility symmetry TCNQ temperature dependence theory thermal tion transfer transition tricritical tricritical points values wall zero