1,3-Alkadiene-Phosphonates, Volume 15
This text examines the formation, physical characteristics and chemical properties of 1,3-alkadienephosphonates with various structures. The special features of P-C bond-forming reactions and methods of forming conjugated multiple bond systems as applied in the synthesis of 1,3-alkadienephosphonates are discussed and the application of physical methods, especially 1H-, 13C- and 31P-NMR and X-ray crystallography, in determining the structures of organophosphorus compounds is demonstrated. The principal reactions of 1,3-alkadienephosphonates are presented.
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1,3-alkadiene-2-phosphonates 1gnatyev 1onin 2-phosphonates acetylene-allene acetylenes acid addition of phosphorus alkadiene alkadienephosphonates AlkO Angelov anionic Arbuzov reaction aromatic atom B.l. and Petrov Berezina Brel carbon carbonium ion catalyst CH,CH CHCH Chem chemical shifts Chemistry chlorides Cl H ClCH2CH Complexes conjugated cyclic derivatives diene Dogadina double bond electron electrophilic addition elimination esters formation formed free radical H C=C H halogen Hirao Homolytic hydrogen halide intermediate isomers ketones lanthanide lanthanide shift lonin Mashljakovskii methods methylene group moiety Molecular multiple bonds Nauk SSSR nucleophilic OAlk Obshch Khim obtained Okhrimenko organophosphorus compounds oxidative chlorophosphonation oxygen P-C bond phonates phos phosphites phosphonate group phosphonates phosphonoprene phosphorus halides phosphorus pentachloride phosphorus trichloride phosphoryl group photoinitiated polymerization polymers proceeds propargyl proton Pudovik reaction of phosphorus reactions of 1,3-alkadienephosphonates reagents regioselectivity Reviews edited Sendjurev solvent stereoselectivity sterically strained structure substitution synthesis of 1,3-alkadienephosphonates triple bond unsaturated compounds Vysokomol Z-isomer Zakharov Zhurn Zhutn