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THE CELL THEORY APPROXIMATION
4 Absorption and Dispersion
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apparent viscosity Barlow calculated shear stress cell theory Chem collision Component Crook decrease defined deformation density describe deviatoric dimensionless direction dyne/cm2 elastic energy equation energy relaxation equations equilibrium experimental expressed Figure free volume function of strain gases hard sphere Helmholtz free energy internal energy jump probability kinetic theory lattice Litovitz Macedo-Litovitz equation Maxwell fluid measured mole molecular jump molecular spacing molecular strain relaxation molecular strain tensor molecules momentum equation Morgan and Kern Newtonian fluid normal stresses obtained oils oscillatory shear partition function Phys potential energy present theory principal axes radial distribution function relaxation region relaxation theory rheological equations Rheology rollers shear modulus shear rate shear stress single relaxation small strains spherical statistical mechanics steady shear flow stress tensor structural relaxation thermodynamic properties tion translational temperature tensor variation velocity viscoelastic xx yy xy xy