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Chemically Initiated Emulsion Polymerization of Vinyl
Radiationinduced Emulsion Polymerization of Vinyl Acetate
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acetate emulsion polymerization aqueous phase benzene calculated chemical initiation concentration of free conversion versus decreases degree of conversion desorption dilatometer dodecylbenzene dose rate effect of emulsifier equation erization experimental free radicals function of conversion g SDBS/1 In-source reactor volume initiator concentration investigation irradiation kinetics krads/h latex light scattering limiting viscosity number micelles molecular weight monomer and polymer monomer droplets monomer-swollen polymer particles monomeric radicals Nomura number of particles number of polymer particle number particles containing plug flow reactor poly vinyl acetate poly(vinyl polymer phase Polymer Sci polymeriz polymerization curve polymerization increases polymerization of vinyl polymerization rate polystyrene radiation-induced experiments radiation-induced polymerization radicals per particle rate constant rate of polymerization ratio refractive index reported SDBS separate monomer phase Smith and Ewart Stannett styrene emulsion polymerization subsection temperature termination rate termination rate constant transfer to monomer versus time curve versus time plots vinyl acetate emulsion vinyl chloride water phase