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Development of the Model
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Amax barrier Brownian motion c/kT calculations chain axis chain length chain of dashpots chain of Maxwell chains with fixed chains with free component correlation length change dashpot of frictional Debye behavior Debye relaxation Debye result derivation diagonal matrix dielectric constant dielectric dispersion dielectric loss dielectric relaxation dilute solutions dispersion curves dispersion region dynamical equations eigenvalue eigenvectors end beads equation II.l4 equation III.9 expression external field fixed ends free ends frictional coefficient function high frequencies high-frequency shoulder Hooke's law I+žA internal rotation lation length loss curves loss peak maximum low frequencies maximum loss Maxwell elements mechanical model molecular monomer monomer unit mutual torque obtain oscillations peak at wt perpendicular dipoles polymer chain polymer molecule Professor Bruno QXQT relaxation process rigid rod rotational diffusion segments of length short chains small molecules spring constant Stoke's Stoke's law summation symmetric torsional springs trigonometric identities values velocity weak springs xmax