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RESULTS AND DISCUSSION cont Page C Storage Modulus 6
THEORY OF GEL FORMATION AND MEASUREMENT OF GEL PROPERTIES
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acrylamide air bearing aqueous average molecular weight calculated chain scission Charlesby Chem Coagulant concentration of polymer cone and plate constant Cornell University cover gas critical concentration crosslink density decrease degassed dilute dose rate Dose received rads dose to gel energy absorbed equation of rubber ethylene oxide experimental filtered freeze-thaw function of dose gel formation gel point gel properties gels formed given concentration incipient gelation increased initial molecular weight intrinsic viscosity irradiation vessel kinetic equation log decrement loss modulus measured modulus versus dose molecular weight distribution nitrogen number of crosslinks observed oxygen oxygen concentration PEO concentration PEO gels PEO samples PEO solution plate viscometer plateau modulus poly poly(ethylene oxide poly(vinyl alcohol polymer chain polymer concentration Proximeter radical formation ring seal rising portion rubber elasticity Sakurada shaft shown in Figure sleeve solvent spacers temperature of irradiation torsion pendulum versus dose received viscoelastic viscometer weight percent