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Free Radical Polymerization Kinetics of Immobilized Chains
KetoEnol Tautomers as Polymerization Initiators
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absorption acid acrylate acrylonitrile active addition anionic aqueous aromatic benzene benzoyl peroxide butadiene calculated catalyst cationic cellulose Chem chemical complex compounds concentration conversion copolymer copolymerization crystalline curves decrease dimer dioxolane double bond effect electron emulsion Equation equilibrium ester ether ethylene experimental films formation formed fraction free radical gegenion glass temperature grafting grams halide increase initiator intrinsic viscosity ion pairs kinetic latex macrocyclic Makromol mechanism merization methyl chloride methyl groups methyl methacrylate mixture mole molecular weight molecular weight distribution molecules monomer observed obtained olefin oxide particles peroxide poly polyamides polymer Polymer Sci polystyrene presence propagation proton pyridine rate constants ratio reaction reactivity reactor samples shown in Figure soluble solution solvent species spectra spectrum stability structure studies styrene surface Table temperature termination tion toluene transfer trioxane U. S. Patent values vinyl acetate vinyl chloride yield