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POLYMER STRUCTURES AND POLYMERIZA
FREE RADICAL POLYMERIZATION
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acetate acid addition polymers alkyl amorphous anionic average molecular weight butadiene calculated carbanion carbon atoms catalyst cationic cell centre Chapter characterization Chem chemical chloride column compounds concentration configuration constant containing copolymer courtesy crosslinking crystalline polymer crystallization curve degradation degree of polymerization density dibenzoyl peroxide diffraction dilute distribution double bond effect end-groups equation equilibrium ethylene experimental Figure fraction free radical free-radical give glass temperature groups hydrogen increase infra-red initiation ionic isoprene isotactic kinetic linear liquid measurements mechanism metal method methyl monomer obtained occur optical osmotic pressure oxide peroxide phase poly polyethylene polymer chain polymer molecule polymethyl methacrylate polystyrene polyvinyl polyvinyl acetate possible precipitation present propagation properties ratio reaction relationship resonance rubber sample scattering scission shown solute molecules solvent stereoregular steric structure studies styrene substituent syndiotactic tacticity technique temperature thermal tion toluene transfer vinyl viscosity volume